Solar Photocatalysis
Semiconductor Photocatalysis is one of the most emerging technologies adopted to address the energy and environmental problems in a self-sustainable manner with the help solar energy. The major limitation of this technology is the unavailability of an efficient photocatalyst for detoxification and disinfection applications.
Titania, Zinc Oxide, Tungsten Oxide, Tin Oxide, Ferric Oxide, etc. are the most widely used semiconductor metal oxide photocatalysts. However, the overall photocatalytic performance of the above metal oxide is limited due to high band gap/low photon absorption/high charge carrier recombination/poor charge transport/inappropriate band edge positions. The performance of the semiconductor metal oxide photocatalyst can be engineered in various ways and our group is focussed on the following methods for improving the overall performance of the photocatalyst.
Metal Oxide heterojunction
In semiconductor photocatalysis heterojunction and its types have a major role in controlling the charge separation and transport. Taking advantage of this, our group is developing/developed highly effective multiphasic homo-heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.
Plasmonic Metal Oxide heterojunction
Surface plasmon assisted semiconductor photocatalysis is one of the most emerging techniques to improve the photon absorption, charge carrier separation and charge transport in a semiconductor. Looking at the improved optical properties of the metal-semiconductor junction, our group is developing/developed highly effective multiphasic plasmonic homo/heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.
Significant Publications
Das, Abinash, Moumita Patra, Muthuraaman Bhagavathiachari, and Ranjith G. Nair. "Defect-induced visible-light-driven photocatalytic and photoelectrochemical performance of ZnO–CeO2 nanoheterojunctions." Journal of Alloys and Compounds 858 (2021): 157730. (Q1, IF:-6.4)
Das, Abinash, P. Mathan Kumar, Muthuraaman Bhagavathiachari, and Ranjith G. Nair. "Hierarchical ZnO-TiO2 nanoheterojunction: A strategy driven approach to boost the photocatalytic performance through the synergy of improved surface area and interfacial charge transport." Applied Surface Science 534 (2020): 147321. (Q1, IF:-7.4)
Nair, Ranjith G., Jetendra K. Roy, S. K. Samdarshi, and A. K. Mukherjee. "Mixed phase V doped titania shows high photoactivity for disinfection of Escherichia coli and detoxification of phenol." Solar energy materials and solar cells 105 (2012): 103-108. (Q1, IF:-7.3)
Nair, Ranjith G., Samrat Paul, and S. K. Samdarshi. "High UV/visible light activity of mixed phase titania: a generic mechanism." Solar energy materials and solar cells 95, no. 7 (2011): 1901-1907. (Q1, IF:-7.3)
Significant Publications
Abinash Das, Trinayana Deka, P Mathan Kumar, M Bhagavathiachari, Ranjith G Nair "Ag-modified ZnO nanorods and its dual application in visible light-driven photoelectrochemical water oxidation and photocatalytic dye degradation: A correlation between optical and electrochemical properties." Advanced Powder Technology 33 (2)(2022), 103434. (Q1, IF:-5.0)
Metal Oxide Nanostructures
Surface area and morphology of the semiconductor photocatalyst have a major role in controlling the photon absorption and charge transport. Taking advantage of this, our group is developing/developed highly effective morphologically tuned multiphasic homo/heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.
Z-Scheme Photocatalysts
In recent years, Direct Z-scheme based photocatalysts has emerged as the most promising one as it maximizes the redox potential and enables effective spatial charge separation. The widely reported g-C3N4-based direct Z-scheme systems includes g-C3N4-wide band gap SCs, g-C3N4-narrow band gap SCs and g-C3N4-based ternary composite. Keeping this in mind, our group tries to identify the challenges and future prospects of g-C3N4-based direct Z-scheme systems for energy and environmental applications.
Significant Publications
Das Abinash, T Deka, PM Kumar, M Bhagavathiachari, RG Nair. "Ag-modified ZnO nanorods and its dual application in visible light-driven photoelectrochemical water oxidation and photocatalytic dye degradation: A correlation between optical and electrochemical properties." Advanced Powder Technology 33 (2)(2022), 103434. (Q1, IF:-5.0)
Das, Abinash, and Ranjith G. Nair. "Effect of aspect ratio on photocatalytic performance of hexagonal ZnO nanorods." Journal of Alloys and Compounds 817 (2020): 153277. (Q1, IF:-6.4)
Das, Abinash, S. K. Nikhil, and Ranjith G. Nair. "Influence of surface morphology on photocatalytic performance of zinc oxide: a review." Nano-Structures & Nano-Objects 19 (2019): 100353. (Q1)
Significant Publications
Suma Das, Soumik Das, Avijit Chowdhury, Ranjith G Nair, Magnetically separable ZnFe2O4 grafted g-C3N4/rGO ternary nanocomposites for enhanced photo-Fenton catalytic activity under visible-light, Materials Today Sustainability 21 (2023):100263. (Q1, IF:-7.2)
Photocatalytic Reaction Parameters
Along with material engineering, the photocatalytic reaction environment also plays a vital role in the photocatalysis process. Keeping this in mind our group is also working on the optimization of photocatalytic reaction parameters such as catalyst loading, reaction temperature, light intensity, dispersion of photocatalyst, dye concentration etc.
Photocatalytic Reactor
Photocatalysis is one of the easy and sustainable technique for water and air treatment. Photocatalysis process in slurry mode are efficient in lab scale but its commercial applicability is limited due to lack of effective separation method for the catalyst. The development efficient photocatalyst alone cannot help the commercialization of the photocatalysis process. It requires an appropriate and efficient photocatalytic reactor with fixed mode catalyst loading and easy replacebility. In this aspect our group is developing fixed mode continuous photocatalytic reactor.
Thin Film Photocatalysis
Fixed mode photocatalytic reactor requires optimized film type catalyst loading. In this process the thickness and surface area of the film have crucial role in deciding its performance. Keeping this in mind our group is working on the preparation of optimized and efficient multiphasic homo/heterojunction metal oxide thin films with various coating techniques such as doctor blade, spin coating , sputtering etc.
Significant Publications
A Das, P Ningthoukhongjam, RG Nair. "A Study on the Crucial Reaction Parameters Involved in Photocatalytic and Sonophotocatalytic Removal of Organic Pollutants ." Water, Air, & Soil Pollution 233 (7)(2022), 1-19. (Q1, IF:-3.0)