Solar Photocatalysis

Semiconductor Photocatalysis is one of the most emerging technologies adopted to address the energy and environmental problems in a self-sustainable manner with the help solar energy.  The major limitation of this technology is the unavailability of an efficient photocatalyst for detoxification and disinfection applications.

Titania, Zinc Oxide, Tungsten Oxide, Tin Oxide, Ferric Oxide, etc. are the most widely used semiconductor metal oxide photocatalysts. However, the overall photocatalytic performance of the above metal oxide is limited due to high band gap/low photon absorption/high charge carrier recombination/poor charge transport/inappropriate band edge positions. The performance of the semiconductor metal oxide photocatalyst can be engineered in various ways and our group is focussed on the following methods for improving the overall performance of the photocatalyst. 

In semiconductor photocatalysis heterojunction and its types have a major role in controlling the charge separation and transport. Taking advantage of this, our group is developing/developed highly effective multiphasic homo-heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.

Surface plasmon assisted semiconductor photocatalysis is one of the most emerging techniques to improve the photon absorption, charge carrier separation and charge transport in a semiconductor. Looking at the improved optical properties of the metal-semiconductor junction, our group is developing/developed highly effective multiphasic plasmonic homo/heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.


Significant Publications

Significant Publications

Surface area and morphology of the semiconductor photocatalyst have a major role in controlling the photon absorption and charge transport. Taking advantage of this, our group is developing/developed highly effective morphologically tuned multiphasic homo/heterojunction composites for efficient solar photocatalytic detoxification and disinfection applications.

In recent years, Direct Z-scheme based photocatalysts has emerged as the most promising one as it maximizes the redox potential and enables effective spatial charge separation. The widely reported g-C3N4-based direct Z-scheme systems includes g-C3N4-wide band gap SCs, g-C3N4-narrow band gap SCs and g-C3N4-based ternary composite. Keeping this in mind, our group tries to identify the challenges and future prospects of g-C3N4-based direct Z-scheme systems for energy and environmental applications.



Significant Publications

Significant Publications


Along with material engineering, the photocatalytic reaction environment also plays a vital role in the photocatalysis process. Keeping this in mind our group is also working on the optimization of photocatalytic reaction parameters such as catalyst loading, reaction temperature, light intensity, dispersion of photocatalyst, dye concentration etc.

Photocatalysis is one of the easy and sustainable technique for water and air treatment. Photocatalysis process in slurry mode are efficient in lab scale but its commercial applicability is limited due to lack of effective separation method for the catalyst. The development efficient photocatalyst alone cannot help the commercialization of the photocatalysis process. It requires an appropriate and efficient photocatalytic reactor with fixed mode catalyst loading and easy replacebility. In this aspect our group is developing fixed mode continuous photocatalytic reactor.

Fixed mode photocatalytic reactor requires optimized film type catalyst loading. In this process the thickness and surface area of the film have crucial role in deciding its performance.  Keeping this in mind our group is working on the preparation of optimized and efficient multiphasic homo/heterojunction metal oxide thin films with various coating techniques such as doctor blade, spin coating , sputtering etc.


Significant Publications